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New Gold-Catalyzed Reactions and Applications for the Synthesis of Alkaloids

ST: NEW GOLD CATALYZED RCTNS & APPLCTNS SYNTHSS ALKLDS

Chemistry

Mathematics & Science

Gt Product Group

Binding Format

Marketing Imprint Name

B2B GT

CL Carton Count

Imprint Name

B2B & B2C

Ana Escribano Cuesta's thesis presents a detailed study of the inter- and intramolecular reactions of carbonyl compounds with 1,6-enynes using gold (I) complexes. An important part of the work involved streamlining the variables that allow the selective synthesis of different products such as tricyclic compounds, dihydropyrans, 1,3-dienes or cyclobutenes. The second chapter highlights the importance and difficulties in synthesising a cyclobutene subunit and the author includes a detailed description of how the products were prepared. The final chapter outlines the synthesis of lundurines using methodology developed by the author's research group for intramolecular gold-catalyzed cyclization of indoles with alkynes. The lundurine products developed in this work show significant in vitro cytoxicity toward B16 melanoma cells. The work in this thesis has led to a number of publications in high-profile chemistry journals.

POST SECONDARY FOUR YEAR

COLFR

COLSO

COLJR

COLSR

Duration

Duration Unit Of Measure

Transaction Type

Front Cover.
Other Frontmatter.
Other Frontmatter.
Title Page.
Copyright Page.
Other Frontmatter.
Dedication.
Supervisor&#x0027;s Foreword.
Contents.
Abbreviations and Acronyms.
1: Introduction.
2: Gold(I)-Catalyzed Reactions of 1,6-Enynes with Aldehydes: Cycloaddition versus Metathesis-Type Reactions.
3: Formation of Cyclobutene Compounds via Gold(I)-Catalyzed Cycloisomerization of 1,n-Enynes.
4: Approach Toward the Total Synthesis of Lundurines.
5: Summary and Outlook.

New Gold-Catalyzed Reactions and Applications for the Synthesis of Alkaloids.css-1p8rvzy{position:absolute;padding-left:8px;}

New Gold-Catalyzed Reactions and Applications for the Synthesis of Alkaloids